Advances in Electrode Design for Enhanced Electrochemical Gas Reduction Reactions: Challenges, Concepts, and Practical Solutions
Kata Kunci:
Electrode design, Electrochemical gas reduction, Sustainable chemical production, Three-electrode system, Energy storage systems.Abstrak
This review paper delves into the imperative role of electrode design in advancing electrochemical gas reduction reactions for sustainable high-value chemical production. The study addresses current challenges in electrode design, introduces the concept of an ideal electrode to tackle these issues, and presents pragmatic strategies for constructing such electrodes based on recent research. The investigation includes the utilization of a three-electrode system comprising WO3 films as the working electrode, Ag/AgCl as the reference electrode, and Pt sheet as the counter electrode immersed in a 1 M PEG:LiI electrolyte. The coloration voltages' impact on WO3 film switching characteristics is scrutinized via the Chronoamperometry (CA) technique. Additionally, the electrochemical exfoliation of graphite into graphene nanosheets is detailed, highlighting the process's observations and outcomes. The research further evaluates six carbon materials as bromine electrodes through a three-electrode half-cell setup, involving pristine and thermally treated conditions. These materials are explored for potential application in energy storage systems, such as lithium-ion batteries and supercapacitors. This paper contributes to the field's understanding by providing insights into electrode material selection, modification methods, and the utilization of computational modeling for performance enhancement.
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