Advancements in Arsenic Removal from Drinking Water using Modified Biosolid Biochars: Adsorption-Desorption Behavior and Recyclability
Keywords:
Arsenic removal, Biosolid biochars, Adsorption-desorption, Modified biochar, Water purificationAbstract
In the pursuit of safe drinking water, mitigating the perilous impact of arsenic contamination has gained paramount significance. The research on effective remediation methods is pivotal, particularly in comprehending the adsorption and desorption dynamics of arsenate (AsV) on modified biochars. This study investigates the adsorption and desorption tendencies of AsV utilizing biosolid-derived biochars, subject to modification with either single iron (Fe) or combined zirconium and iron (Zr–Fe). The biochars, namely Fe-chips (FeBSBC), Fe-salt (FeCl3BSBC), and Zr–Fe-salt (Zr–FeCl3BSBC) modified, were subjected to rigorous examination through various analytical techniques. Notably, X-ray photoelectron spectroscopy revealed the conversion of pentavalent AsV to the more hazardous trivalent AsIII form with FeCl3BSBC and Zr–FeCl3BSBC modifications. Equilibrium adsorption studies indicated substantial increases in AsV adsorption capacities, reaching 27.4 mg/g (pH 5) for FeBSBC, 29.77 mg/g (pH 5) for FeCl3BSBC, and 67.28 mg/g (pH 6) for Zr–FeCl3BSBC. Co-existing anions exhibited a varying influence on AsV removal efficacy. Moreover, a positive correlation with temperature demonstrated the endothermic nature of the adsorption process. Desorption and recyclability experiments exhibited the potential of the modified biochars for multiple cycles of AsV removal. This investigation presents a comprehensive insight into arsenic remediation through modified biosolid biochars, elucidating their adsorption behavior, recyclability, and potential for sustainable water purification solutions.
References
Rathi, B. S., & Kumar, P. S. (2021). A review on sources, identification and treatment strategies for the removal of toxic Arsenic from water system. Journal of Hazardous Materials, 418, 126299.
Yadav, M. K., Saidulu, D., Gupta, A. K., Ghosal, P. S., & Mukherjee, A. (2021). Status and management of arsenic pollution in groundwater: A comprehensive appraisal of recent global scenario, human health impacts, sustainable field-scale treatment technologies. Journal of Environmental Chemical Engineering, 9(3), 105203.
Singh, P., Borthakur, A., Singh, R., Bhadouria, R., Singh, V. K., & Devi, P. (2021). A critical review on the research trends and emerging technologies for arsenic decontamination from water. Groundwater for Sustainable Development, 14, 100607.
Mukhopadhyay, A., Duttagupta, S., & Mukherjee, A. (2022). Emerging organic contaminants in global community drinking water sources and supply: A review of occurrence, processes and remediation. Journal of Environmental Chemical Engineering, 10(3), 107560.
Pradhan, B., Chand, S., Chand, S., Rout, P. R., & Naik, S. K. (2023). Emerging groundwater contaminants: A comprehensive review on their health hazards and remediation technologies. Groundwater for Sustainable Development, 20, 100868.
Gani, K. M., Hlongwa, N., Abunama, T., Kumari, S., & Bux, F. (2021). Emerging contaminants in South African water environment-a critical review of their occurrence, sources and ecotoxicological risks. Chemosphere, 269, 128737.
Omran, B. A., & Baek, K. H. (2022). Valorization of agro-industrial biowaste to green nanomaterials for wastewater treatment: Approaching green chemistry and circular economy principles. Journal of Environmental Management, 311, 114806.
Duan, Y., Tarafdar, A., Kumar, V., Ganeshan, P., Rajendran, K., Giri, B. S., ... & Awasthi, M. K. (2022). Sustainable biorefinery approaches towards circular economy for conversion of biowaste to value added materials and future perspectives. Fuel, 325, 124846.
Ambika, S., Kumar, M., Pisharody, L., Malhotra, M., Kumar, G., Sreedharan, V., ... & Bhatnagar, A. (2022). Modified biochar as a green adsorbent for removal of hexavalent chromium from various environmental matrices: mechanisms, methods, and prospects. Chemical Engineering Journal, 439, 135716.
Manikandan, S., Vickram, S., Subbaiya, R., Karmegam, N., Chang, S. W., Ravindran, B., & Awasthi, M. K. (2023). Comprehensive review on recent production trends and applications of biochar for greener environment. Bioresource Technology, 129725.
Ullah, H., Chen, B., Rashid, A., Zhao, R., Shahab, A., Yu, G., ... & Khan, S. (2023). A critical review on selenium removal capacity from water using emerging non-conventional biosorbents. Environmental Pollution, 122644.
Kumar, K., Kumar, R., Kaushal, S., Thakur, N., Umar, A., Akbar, S., ... & Baskoutas, S. (2023). Biomass waste-derived carbon materials for sustainable remediation of polluted environments: A comprehensive review. Chemosphere, 140419.
Song, G., Gao, R., Zhao, Z., Zhang, Y., Tan, H., Li, H., ... & Feng, M. (2022). High-spin state Fe (III) doped TiO2 for electrocatalytic nitrogen fixation induced by surface F modification. Applied Catalysis B: Environmental, 301, 120809.
Peng, X., Wu, J., Zhao, Z., Wang, X., Dai, H., Xu, L., ... & Hu, F. (2022). Activation of peroxymonosulfate by single-atom Fe-g-C3N4 catalysts for high efficiency degradation of tetracycline via nonradical pathways: Role of high-valent iron-oxo species and Fe–Nx sites. Chemical Engineering Journal, 427, 130803.
Yang, C., Shang, S., Gu, Q., Shang, J., & Li, X. Y. (2022). Metal-organic framework-derived carbon nanotubes with multi-active Fe-N/Fe sites as a bifunctional electrocatalyst for zinc-air battery. Journal of Energy Chemistry, 66, 306-313.
Rahidul Hassan, H. (2023). A review on different arsenic removal techniques used for decontamination of drinking water. Environmental Pollutants and Bioavailability, 35(1), 2165964.
Lewoyehu, M. (2021). Comprehensive review on synthesis and application of activated carbon from agricultural residues for the remediation of venomous pollutants in wastewater. Journal of Analytical and Applied Pyrolysis, 159, 105279.
ALSamman, M. T., Sotelo, S., Sánchez, J., & Rivas, B. L. (2022). Arsenic oxidation and its subsequent removal from water: An overview. Separation and Purification Technology, 123055.
Qasem, N. A., Mohammed, R. H., & Lawal, D. U. (2021). Removal of heavy metal ions from wastewater: A comprehensive and critical review. Npj Clean Water, 4(1), 36.
Fei, Y., & Hu, Y. H. (2023). Recent progress in removal of heavy metals from wastewater: A comprehensive review. Chemosphere, 139077.
S. Mandar, D. Purnamsari, and R. Zainul, “Chataliytic activity of nano ZnO/Cu for degradation humic acid under ilumination outdoor light,” J. Phys. Conf. Ser., vol. 1481, no. 1, 2020, doi: 10.1088/1742-6596/1481/1/012038.
R. Zainul, A. Alif, H. Aziz, S. Arief, Syukri, and A. Yasthopi, “Photoelectrosplitting water for hydrogen production using illumination of indoor lights,” J. Chem. Res., vol. 7, no. 11, pp. 57–67, 2015.
Rahmawati, F., Heliani, K. R., Wijayanta, A. T., Zainul, R., Wijaya, K., Miyazaki, T., & Miyawaki, J. (2023). Alkaline leaching-carbon from sugarcane solid waste for screen-printed carbon electrode. Chemical Papers, 77(6), 3399-3411.
Tamarani, R. Zainul, and I. Dewata, “Preparation and characterization of XRD nano Cu-TiO2 using sol-gel method,” J. Phys. Conf. Ser., vol. 1185, no. 1, 2019, doi: 10.1088/1742-6596/1185/1/012020.
G. E. Putri, S. Arief, N. Jamarun, F. R. Gusti, and R. Zainul, “Microstructural analysis and optical properties of nanocrystalline cerium oxides synthesized by precipitation method,” Rasayan J. Chem., vol. 12, no. 1, pp. 85–90, 2019, doi: 10.31788/RJC.2019.1215029.
Mohd Yazid, S. N. A., Md Isa, I., Ali, N. M., Hashim, N., Saidin, M. I., Ahmad, M. S., ... & Zainul, R. (2022). Graphene/iridium (III) dimer complex composite modified glassy carbon electrode as selective electrochemical sensor for determination of hydroquinone in real-life water samples. International Journal of Environmental Analytical Chemistry, 102(11), 2607-2624.
R. Zainul, B. Oktavia, I. Dewata, and J. Efendi, “Study of Internal Morphology on Preparation of Cu2OThin-Plate using Thermal Oxidation,” J. Phys. Conf. Ser., vol. 1116, no. 4, 2018, doi: 10.1088/1742-6596/1116/4/042046.
Oktavia, B., Tilla, M., Nasra, E., Zainul, R., & Amin, M. (2021, February). Activation and Modification of Natural Silica for Anion Adsorbent. In Journal of Physics: Conference Series (Vol. 1788, No. 1, p. 012013). IOP Publishing.
R. N. Maurani, D. Purnamasari, and R. Zainul, “Preparation of TiO2 thin layer on ceramics using dip coating method for degradation humic acid,” J. Phys. Conf. Ser., vol. 1481, no. 1, pp. 2–10, 2020, doi: 10.1088/1742-6596/1481/1/012033.
R. Zainul, “Zinc / Aluminium-Quinclorac Layered Nanocomposite Modified Multi-Walled Carbon Nanotube Paste Electrode for Electrochemical Determination of Bisphenol A,” 2021.
G. Eka Putri, F. Rahayu Gusti, A. Novita Sary, and R. Zainul, “Synthesis of silver nanoparticles used chemical reduction method by glucose as reducing agent,” J. Phys. Conf. Ser., vol. 1317, no. 1, 2019, doi: 10.1088/1742-6596/1317/1/012027.
R. Zilla, D. Purnamasari, and R. Zainul, “Design of rotary photoreactor using nano Cu/TiO2 for degradation humic acid in outdoor visible light,” J. Phys. Conf. Ser., vol. 1481, no. 1, 2020, doi: 10.1088/1742-6596/1481/1/012039.
R. Zainul et al., “Magnesium layered hydroxide-3-(4-methoxyphenyl) propionate modified single-walled carbon nanotubes as sensor for simultaneous determination of Bisphenol A and Uric Acid,” Int. J. Electrochem. Sci., vol. 16, pp. 1–12, 2021, doi: 10.20964/2021.09.15.
Oktavia, B., Ramadhani, I., & Zainul, R. (2023, April). Synthesis of sodium silicate (Na2SiO3) from natural silica using sodium hydroxide (NaOH). In AIP Conference Proceedings (Vol. 2673, No. 1). AIP Publishing.
Zainul, R., Oktavia, B., Dewata, I., & Efendi, J. (2018, April). Thermal and Surface Evaluation on The Process of Forming a Cu2O/CuO Semiconductor Photocatalyst on a Thin Copper Plate. In IOP Conference Series: Materials Science and Engineering (Vol. 335, No. 1, p. 012039). IOP Publishing.
Lestari, I., Ramadhanty, Y., Marlinda, L. . and Ngatijo, N. (2021) “Preparation and Characterization of Magnetite Fe3O4-Activated Carbon Composite as Adsorbent Cr(VI) Ion ”, EKSAKTA: Berkala Ilmiah Bidang MIPA, 22(4), pp. 238-247. doi: 10.24036/eksakta/vol22-iss4/284.
Supu, I., Setiawan, D. G. E., Latief, M. F., Ismail, S. Y. N. and Sari, Y. I. (2022) “Morphology and Optical Properties Analysis of Cu2+ Doped ZnO for Preparation Dye Sensitized Solar Cell (DSSC)”, EKSAKTA: Berkala Ilmiah Bidang MIPA, 23(03), pp. 211-222. doi: 10.24036/eksakta/vol23-iss03/330.
Rahmi, S. T., Rahmad, E. U. ., Purnamasari, D. and Zainul, R. (2023) “Electrolyte Optimization Study on Dry Cell Generator Electrolysis System for Producing Hydrogen Gas Using RSM Method (Response Surface Method)”, EKSAKTA: Berkala Ilmiah Bidang MIPA, 24(02), pp. 226-236. doi: 10.24036/eksakta/vol24-iss02/273.
Riski Gusti, D. ., Mastutik, D. ., Lestari, I. and Walidatur Rofiah, Y. (2021) “The Effect of Graphite Concentration in TiO2 Semiconductors on Efficiency of Dye Sensitized Solar Cells (DSSC) Using Dye Melastoma malabathricum L Fruit Extract”, EKSAKTA: Berkala Ilmiah Bidang MIPA, 22(1), pp. 10-17. doi: 10.24036/eksakta/vol22-iss1/258.
Hamid, A., Rahmawati, Z., Abdullah, M., Purbaningtyas, T. E., Rohmah, F. and Febriana, I. D. (2022) “The Influence of NaOH Activator Concentration on the Synthesis of Activated Carbon from Banana Peel for Pb(II) Adsorption”, EKSAKTA: Berkala Ilmiah Bidang MIPA, 23(03), pp. 158-166. doi: 10.24036/eksakta/vol23-iss03/323.
